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Conformational equilibrium isotope effects for hydrogen in cyclohexanones and other ketones are consistent with (i) hyperconjugation, (ii) analogues of hyperconjugation, and (iii) a difference in polarity between C-H and C-D bonds; steric effects are relatively unimportant. © 1989.

Original publication

DOI

10.1016/S0040-4039(01)80752-8

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

01/01/1989

Volume

30

Pages

4589 - 4592