Cookies on this website
We use cookies to ensure that we give you the best experience on our website. If you click 'Continue' we will assume that you are happy to receive all cookies and you will not see this message again. Click 'Find out more' for information on how to change your cookie settings.

Conformational equilibrium isotope effects in derivatives of 1,3-dioxan are consistent with four distinct origins: (i) steric hindrance, (ii) the anomeric effect, (iii) orbital interactions between C-H bonds and either non-bonding electrons through three or more coplanar bonds or (C-O)σ* orbitals, and (iv) a difference in polarity between C-H and C-D. © 1989.

Original publication

DOI

10.1016/S0040-4039(01)80751-6

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

01/01/1989

Volume

30

Pages

4585 - 4588