The origin of conformational equilibrium isotope effects for carbon

Carr CA.; Robinson MJT.; Young DJ.

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The origin of conformational equilibrium isotope effects for carbon

Carr CA., Robinson MJT., Young DJ.

Conformational equilibrium isotope effects for carbon are dominated by orbital interactions between CC bonds and strong acceptor (the η* in CO) or strong donor (the nonbonding electrons on O) groups, and show a small dependence upon solvent polarity. © 1989.

Original publication

DOI

10.1016/S0040-4039(01)80753-X

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

01/01/1989

Volume

Pages

4593 - 4596