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Conformational equilibrium isotope effects for carbon are dominated by orbital interactions between CC bonds and strong acceptor (the η* in CO) or strong donor (the nonbonding electrons on O) groups, and show a small dependence upon solvent polarity. © 1989.

Original publication

DOI

10.1016/S0040-4039(01)80753-X

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

01/01/1989

Volume

30

Pages

4593 - 4596